The death toll climbed to 12,369 after 47 more patients died from the viral disease, the DOH said.
It added 144 more patients recovered, raising the total number of recoveries to 534,463.
The Philippines, which has about 110 million population, has tested over 8 million people since the disease emerged in January last year.
The Philippines began its vaccination drive against COVID-19 on Monday, less than a day after the arrival of a batch of China's coronavirus vaccines.
Presidential spokesperson Harry Roque hailed the vaccination drive as "very successful."
"Everyone celebrated. Others even shed tears of joy at the PGH (the Philippine General Hospital), especially when they saw Doctor Legaspi getting the jabs," he told a televised press conference.
"Our medical frontliners are happy because they now have peace of mind that they have protection despite their exposure to the coronavirus," Roque added.
Health Secretary Francisco Duque said that Monday's rollout of the Sinovac vaccine CoronaVac that China donated to the Philippines was "heartwarming" and "quite satisfactory."
"There was much pride and joy in seeing that the health care workers have started to receive the vaccination, protection against COVID-19. It was heartwarming to witness the historic event," Duque said on TV Tuesday.
Duque said 756 Filipinos received the CoronaVac vaccines administered in six hospitals across Metro Manila on the first day.
Duque said the government deployed CoronaVac to about 12 hospitals on the second day of the vaccination drive. He added the government will also start rolling out the vaccines in hospitals in the central and southern Philippines.
PGH Director Gerardo Legaspi, the first Filipino to receive the Chinese-made CoronaVac vaccine, said he felt "excited" to see a long line of health workers queueing to get the vaccine on the second day of the vaccination drive.
"I feel excited again because I saw the long line of (health workers) outside waiting for their turn today," Legaspi said.
Legaspi said the PGH administered the vaccine to 128 people on day one. "We planned to vaccinate 50, but surprisingly 128 came on Monday," he said, adding that the PGH will administer jabs to around 200 on Tuesday.
The government aims to inoculate up to 70 million Filipinos this year to achieve herd immunity, starting with health care workers, the elderly, and the poor communities.
The Philippines is negotiating to buy over 160 million vaccine doses from different pharmaceutical firms this year, including Sinovac.
"Our aim is for the Philippines to be free from Covid-19 by 2022," said Defense Secretary Delfin Lorenzana, the chair of the national Covid-19 task force. - Xinhua